In chemistry, the chemical yield, the yield of the reaction, or only the rendement refers to the amount of reaction product produced in the chemical reaction. [1] Absolute rendement can be written as weight in grams or in moles (molar yield). The relative yield used as a calculation of the effectiveness of the procedure is calculated by dividing the amount of product obtained in moles by the theoretical yield in moles:
Fractional yield = actual rendement divided by
theoretical rendement
To obtain a percentage yield, multiply the fractional yield by 100%.
One or more reactants in chemical reactions are often used redundantly. The theoretical rendement is calculated based on the number of moles of the limiting reagent. For this calculation, it is usually assumed that there is only one reaction involved.
The ideal chemical yield value (theoretical rendement) is 100%, a value highly unlikely to be achieved in its practice. Calculate the percentage of rendement that is by using the following equations percent rendemen = weight yield / weight of yield divided by the sample weight multiplied by 100%
To obtain a percentage yield, multiply the fractional yield by 100%.
One or more reactants in chemical reactions are often used redundantly. The theoretical rendement is calculated based on the number of moles of the limiting reagent. For this calculation, it is usually assumed that there is only one reaction involved.
The ideal chemical yield value (theoretical rendement) is 100%, a value highly unlikely to be achieved in its practice. Calculate the percentage of rendement that is by using the following equations percent rendemen = weight yield / weight of yield divided by the sample weight multiplied by 100%
In stoichiometry there is a special note on
Theoretical results, tangible results, and percent of results
Theoretical results, tangible results, and percent of results
- Theoretical results are the amounts calculated from the balanced chemical equations or how many products are derived based on stoichiometric calculations.
- The real or actual result is the number of results actually generated in a chemical reaction or how many products are obtained after the reaction is complete.
- Efficiency of chemical reaction can be determined through percentage of result or percentage of rendemen that is: Percent of result: (result of real / theoretical result) x 100%
Here is an example of rendemen
1. If the reaction between 6 grams of ethane C2H6 (Mr = 30) with 7.1 grams of Cl2 (Mr = 71) yields 5.16 grams of C2H6Cl (Mr = 64.5) then the percentage of ethylchloride rendement is ...
Answer:
In this case we are required to calculate% C2H6Cl, so let's compare facts and theories:
FACT:
The resulting C2H6Cl period = 5.16 grams

THEORY:
We look for the C2H6Cl period that results from the reaction

The reaction is happening
1. If the reaction between 6 grams of ethane C2H6 (Mr = 30) with 7.1 grams of Cl2 (Mr = 71) yields 5.16 grams of C2H6Cl (Mr = 64.5) then the percentage of ethylchloride rendement is ...
Answer:
In this case we are required to calculate% C2H6Cl, so let's compare facts and theories:
FACT:
The resulting C2H6Cl period = 5.16 grams
THEORY:
We look for the C2H6Cl period that results from the reaction
The reaction is happening
2. Synthesis
of aspirin
Ways of working
• A total of 2.8 g of salicylic acid was incorporated into a 125 mL erlenmeyer. Then 8 mL of acetic anhydride was added while rinsing. Added also 85% H3PO4 catalyst as a hydration agent of 0.5 mL, after which it is heated.
• Next, After 5 minutes lifted and 4 mL of aquades added. Waited for 6 minutes, then added 40 mL aquades. Let up to crystallize (if not crystallized, wall-casting with stirring rods)
• Added 100 mL cold aquades. Wait until crystals form
Calculation of rendemen
• Once obtained the crystal then weighed and calculated rendemen
• In the experiment used salicylic acid as much as 2.8 g, so salicylic acid mole can be calculated, that is 2.8 / 138 = 0.02 mol.
• The resulting aspirin can be calculated theoretically ie the mole of aspirin multiplied by its Mr.
Mol aspirin = mol salicylic acid = 0.02 mol.
Gram of aspirin is theoretically 0.02 x 180 = 3.6 grams.
• From the experiments generated aspirin as much as 2.4 grams, then the crystal is taken and calculated rendemennya.
Then rendemennya:
(Mass of experimental results / theoretical mass) x 100% =
(2.4 grams / 3.6 grams) x 100% = 66.67%.
Ways of working
• A total of 2.8 g of salicylic acid was incorporated into a 125 mL erlenmeyer. Then 8 mL of acetic anhydride was added while rinsing. Added also 85% H3PO4 catalyst as a hydration agent of 0.5 mL, after which it is heated.
• Next, After 5 minutes lifted and 4 mL of aquades added. Waited for 6 minutes, then added 40 mL aquades. Let up to crystallize (if not crystallized, wall-casting with stirring rods)
• Added 100 mL cold aquades. Wait until crystals form
Calculation of rendemen
• Once obtained the crystal then weighed and calculated rendemen
• In the experiment used salicylic acid as much as 2.8 g, so salicylic acid mole can be calculated, that is 2.8 / 138 = 0.02 mol.
• The resulting aspirin can be calculated theoretically ie the mole of aspirin multiplied by its Mr.
Mol aspirin = mol salicylic acid = 0.02 mol.
Gram of aspirin is theoretically 0.02 x 180 = 3.6 grams.
• From the experiments generated aspirin as much as 2.4 grams, then the crystal is taken and calculated rendemennya.
Then rendemennya:
(Mass of experimental results / theoretical mass) x 100% =
(2.4 grams / 3.6 grams) x 100% = 66.67%.
Why we have to predict rendement of product a reaction ?
BalasHapusTo get the ideal chemical value and can predict whether what has been done is correct according to the competency standard and to be able to reduce errors in the calculation.
HapusWhy do we need to predict the yield of a reaction?
BalasHapusbecause the reaction should theoretically produce as many products as the stoichiometric ratio of the reactants limiting product. This amount can be calculated and called theoretical results. However, the actual number of products produced by the reaction will usually be less than the theoretical results and referred to as the actual results. This is because the reactions often have "side reactions" that compete for reactants and produce undesirable products. To evaluate the efficiency of the reaction, the chemist compares the theoretical and actual results by calculating the percentage of the reaction: Fractional yield = actual rendement divided by theoretical rendement.
Hapusplease explain again looking for rendement of synthesis aspirin like the first experiment !
BalasHapusAspirin is the result of salicylic acid synthesis with acetic anhydride. Aspirin is a group of glycoside compounds, which function as a more perfect antipyretic and analgesic than salicylic acid. In addition to being a more perfect antipyretic and analgesic, this aspirin is a standard drug (reference for other pain medications), in which the work system inhibits the production of prostaglandins (specific substances that cause pain and fever) to reduce the body's response to a series of chemical processes that eventually form Pain. In addition, aspirin can also reduce the risk of death by 25% for cancer patients compared with salicylic acid consumption.
HapusCalculation of rendemen
· Once obtained the crystal then weighed and calculated rendement
· In the experiment used salicylic acid as much as 2.8 g, so that salicylic acid mole can be calculated, that is 2,8 / 138 = 0,02 mol.
· The resulting aspirin can be calculated theoretically ie the mole of aspirin multiplied by its Mr.
Mol aspirin = mol salicylic acid = 0.02 mol.
Gram of aspirin is theoretically 0.02 x 180 = 3.6 grams.
· From the experiments generated aspirin as much as 2.4 grams, then the crystal is taken and calculated rendemennya.
Then rendemennya:
(Mass of experimental results / theoretical mass) x 100% =
(2.4 grams / 3.6 grams) x 100% = 66.67%.
Why In the experiment Synthesis of aspirin used salicylic acid? Can it be replaced with another?
BalasHapusAspirin is a salicylic acid derived compound that can be synthesized by an esterification reaction. Salicylic acid was dissolved in acetic acid anhydra resulting in substitution of hydroxy group (-OH) in salicylic acid with acetyl group (OCOCH3) on acetic anhydra. As a catalyst, sulfuric acid is used. This reaction will produce aspirin as the main product and acetic acid as a by-product.
Hapus